6,8-二甲基-1,2,4-三唑并嘧啶-3-丁二酮基硫醚酮-烯醇互变异构平衡的1HNMR研究

用１ＨＮＭＲ方法研究了不同溶剂和温度对６，８－二甲基－１，２，４－三唑并嘧啶－３－丁二酮基硫醚酮－烯醇互变异构平衡的影响，发现温度升高有利于平衡向酮式转变，而溶剂极性的改变对平衡的影响并不规律，获得了四种溶剂中的ΔＨ和ΔＳ．     

强激光等离子体中光子的运动

通过严格求解广义协变的光子运动的测地线方程,讨论了准静态时一线等温膨胀的自洽激光等离子体中光子的运动.用数值方法得到了光子速度的空间分布曲线. 关键词：     

巯基棉富集─火焰原子吸收分光光度法测定水中的微量铁

本文详细考查了巯基棉富集Ｆｅ（Ⅲ）的条件，发现微量铁（Ⅲ）在ｐＨ值为５－８的条件下能为巯基棉定量吸附．１ｍｏｌ／Ｌ盐酸５ｍＬ能将巯基棉吸附的Ｆｅ（Ⅲ）定量洗脱，０．１ｇ巯基棉的饱和吸附量为９０μｇ，样品分析测定结果的相对标准偏差小于３．４％，９８．４％－９８．８％。     

杨村煤与石油渣油共处理高温缩聚反应特性的研究

用ＧＪ－２型微型反应釜研究了兖州杨村煤与石油渣油在４７０℃时共处理反应的特性，结果表明，杨树煤和石油渣油在高温下进行共处理反应时，宏观表现是缩聚反应占主导地位，程序升温可提高煤的转化率，添加四氢萘到石油渣油中可抑制缩聚反应，而且添加量越大，抑制效果越明显，煤液化产物的重新加氢也会发生一定的缩聚反应，可产生微量结渣。     

对过程e~＋e~－→J／ψ→γ＋X（J~（PC），X→BB（重子，反重子）的角分布和共振态X的自旋－宇称分析

用螺旋度角分布方法对过程ｅ＋ｅ－～Ｊ／ψ→γ＋Ｘ（ＪＰＣ）→ＢＢ（重子，反重子）进行了分析，得到了Ｘ具有不同自旋─—宇称时角分布及投影角分布的形式，从而可以通过对实验数据的分析来确定共振态Ｘ的自旋性质．     

Brownian diffusion in a nonuniform gas

An analysis is made of the effects on the diffusion of Brownian particles whose Knudsen number is large compared to unity, of nonuniformities in the host gas. As examples, in one type of nonuniformity of the host gas, the Chapman-Enskog velocity distribution function for the gas molecules is used; in the other, the host gas is a free-molecule Couette flow. In both cases, a new force on the Brownian particles appears. Two techniques are used (extending Kramers' method and utilizing the Chapman-Enskog method) to transform the new Fokker-Planck equation into generalized Smoluchowski and convective diffusion equations. In these equations, the diffusion coefficient appears as a second-order tensor. Thus, it is demonstrated that Brownian diffusion in a nonuniform gas is anisotropic.The work of Slinn was financially supported in part by Battelle Memorial Institute and in part by U.S. Atomic Energy Commission Contract AT(45-1)-1830. The work of Shen was supported in part by U.S. Air Force Office of Scientific Research Contract 49(638)-1346.     

亚硫酸四氟乙二醇酯的环断裂反应

含有亚硫酸四氟乙二醇酯(1)的四氟乙烷磺内酯(2)与H(CF_2)_4CH_2OH和三乙胺反应可获得草酸酯(CO_2CH_2CF_2CF_2—CF_2CF_2H)_2(3)。化合物(3)生成的机理解释为由于1的破环,生成了SOF_2和(COF)_2,后者进一步与H(CF_2)_4CH_2OH反应生成3。 3与二乙胺反应生成Et_2NCOCO_2CH_2(CF_2)_4H(4)。3和4皆为新化合物。     

COMPLETE SUBMANIFOLDS IN E~(n+p)WITH PARALLEL MEAN CURVATURE

This paper gives a pinching condition by which complete submanifolds in aEuclidean space can be classified completely.In particular,a characterization for acomplete submanifold in a Euclidean space to be totally umbilical is shown.     

Optical spectra of CsI,CsBr, ZuGeP2, and SbSI

We report here the study of the normal reflectivity spectra R and the corresponding derivative spectra (1/R) dR/dE of SbSI between 2 and 6 eV. The spectra show very strong anisotropy. We have also tried to use the change of the wavelength modulation spectrum to monitor the change in the band structure of SbSI due to the phase transition at 292 °C (D_2h¹⁶→C_2v⁹). Careful examination of the spectra at various temperatures around T_c shows no observable change. We report also the wavelength-modulated reflectivity spectra of the chalcopyrite crystal ZnGeP₂ at 5 K between 2 and 6 eV, for E∥ C and E⊥ C. The experimental results are compared with the theoretical band structure calculation by de Alvarez and Cohen. We also present measurements on CsBr, CsI in the vacuum uv (between 5 and 8 eV) at 1.8K, showing noticeable difference with previous reflectivity measurements at 77 K.     

In vacuo photocurrent measurements of plasma polymerized styrene films

Photoconductivity measurements were carried out on plasma polymerized styrene (PPS) in vacuo, in air, and in subsequently re-evacuated conditions. Samples with two gold electrodes (Au-PPS-Au) and gold-aluminum electrodes (Au-PPS-Al) were used. Positive short circuit photocurrents in the direction of illumination were observed in both types of specimens. In the case of Au-PPS-Au, photocurrent threshold was about 1.6 eV in vacuo for the virgin film, which is attributed to the energy of hole generation in bulk. Residual free radicals were assumed to be the acceptors in this mechanism. In the case of Au-PPS-Al, electron injection from aluminum was thought to be a more likely mechanism, with an estimated barrier height of approximately 2.6 eV.